Problem Set H– Elimination Reactions
Instructions: Complete all problems prior to the deadline. Upload to the Problem Set H
assignment on Canvas. After the key posts, correct your problem set, and upload your
corrections as a second upload to the Problem Set H assignment.
Part 1: Smith Problems
Problems from “Organic Chemistry” 6 ed by Janice Smith.
1. Draw the structures of two different alkyl halides that yield the alkene as the only
product.
Alkyl Halide 1 Alkyl Halide 2
mechanism as E1 or E2.
E1 or
E2?
why.
4. Draw the structure, including stereochemistry, of an alkyl chloride that forms
each alkene as the exclusive E2 product.
.
6. Draw the structure of a dihalide that could be used to prepare the alkene. There
may be more than one possible.
7. Draw all of the substitution and elimination products formed when the alkyl
halide below is treated with a) CH3OH and b) KOH. Indicate stereochemistry of
products, as well as mechanisms of formation.
and draw the structure of the major product actually formed.
are formed in the following reaction:
Product 1:
Product 2:
Product 3:
Product 4: